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TBS-DHG Catalyst
产品别名
212120-61-1
TBS-DHG Catalyst
6-Tertbutyldimethylsilyl-1,2-dihydroglucal
(2R,3S,4R)-2-(((tert-Butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-3,4-diol
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C12H26O4Si |
Molecular weight | 262.42 |
General description【一般描述】 | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
Application【应用】 | 6-Tertbutyldimethylsilyl-1,2-dihydroglucal (TBS-DHG) was reported by the Morken Lab to be an effective carbohydrate-derived catalyst for enantioselective diboration of alkenes. Related capabilities were observed with the dihydrorhamnal (DHR) catalyst (901237). TBS-DHG has also been used in ruthenium(0)catalyzed transfer hydrogenation cycloadditions. |
Other Notes【其他说明】 |
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产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | ≥95% |
form【形式】 | powder or crystals |
reaction suitability | reagent type: catalyst |
greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
greener alternative category【环保替代产品分类】 | Aligned |
storage temp.【储存温度】 | −20℃ |
SMILES string | [H]C1([H])C([H])([H])O[C@@](C([H])([H])O[Si](C([H])([H])[H])(C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])([H])[C@](O[H])([H])[C@]1([H])O[H] |
安全信息
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |