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TBS-DHG Catalyst

产品编号:4151721
规格:≥95%
CAS NO:212120-61-1
包装规格:100 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
4151721100 MG1950
产品别名

212120-61-1

TBS-DHG Catalyst

6-Tertbutyldimethylsilyl-1,2-dihydroglucal

(2R,3S,4R)-2-(((tert-Butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-3,4-diol

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C12H26O4Si
Molecular weight
262.42
General description【一般描述】
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application【应用】
6-Tertbutyldimethylsilyl-1,2-dihydroglucal (TBS-DHG) was reported by the Morken Lab to be an effective carbohydrate-derived catalyst for enantioselective diboration of alkenes. Related capabilities were observed with the dihydrorhamnal (DHR) catalyst (901237). TBS-DHG has also been used in ruthenium(0)catalyzed transfer hydrogenation cycloadditions.
Other Notes【其他说明】
  • Carbohydrate-Catalyzed Enantioselective Alkene Diboration:Enhanced Reactivity of 1,2-Bonded Diboron Complexes
  • Diols, α-Ketols, and Diones as 22π Components in [2+2+2] Cycloadditions of 1,6-Diynes via Ruthenium(0)-Catalyzed Transfer Hydrogenation
  • Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope
产品性质
Quality Level【质量水平】
100
Assay【测定】
≥95%
form【形式】
powder or crystals
reaction suitability
reagent type: catalyst
greener alternative product characteristics【环保替代产品特性】
Catalysis
Learn more about the Principles of Green Chemistry.
greener alternative category【环保替代产品分类】
Aligned
storage temp.【储存温度】
−20℃
SMILES string
[H]C1([H])C([H])([H])O[C@@](C([H])([H])O[Si](C([H])([H])[H])(C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])([H])[C@](O[H])([H])[C@]1([H])O[H]
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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