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SLAP M

产品编号:4151563
规格:≥95%
CAS NO:2093935-94-3
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
4151563500 MG2110
产品别名

2093935-94-3

SLAP M

2-((Trimethylsilyl)methoxy)ethan-1-amine

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C6H17NOSi
Molecular weight
147.29
Application【应用】
When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.
Other Notes【其他说明】
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
产品性质
Quality Level【质量水平】
100
Assay【测定】
≥95%
form【形式】
liquid
storage temp.【储存温度】
2-8℃
SMILES string
NCCOC[Si](C)(C)C
安全信息
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
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