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SLAP HydroPyrrolopyrazine Reagent
产品别名
SLAP HydroPyrrolopyrazine Reagent
(S)-(1-((Trimethylsilyl)methyl)pyrrolidin-2-yl)methanamine
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C9H22N2Si |
| Molecular weight | 186.37 |
| NACRES | NA.22 |
| Application【应用】 | Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6 (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis. |
| Other Notes【其他说明】 |
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产品性质
| form【形式】 | liquid |
| Quality Level【质量水平】 | 100 |
| density | 0.8846 g/mL |
| storage temp.【储存温度】 | −20℃ |
| packaging【包装】 | 500 mg in amber glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 10 - Combustible liquids |
| WGK | WGK 3 |
| Flash Point(F)【闪点(F)】 | 177.8 °F |
| Flash Point(C)【闪点(C)】 | 81 ℃ |
