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Rh2(R-PTAD)4

产品编号:4151440
CAS NO:909393-65-3
包装规格:50 MG,250 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
415144050 MG1102
4151440250 MG3720
产品别名

909393-65-3

Rh2(R-PTAD)4

Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C80H80N4O16Rh2
Molecular weight
1559.32
Application【应用】
This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control.
Other Notes【其他说明】
Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid Reactions

Asymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] Cycloaddition

Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E
产品性质
form【形式】
powder or crystals
mp
>300 ℃
安全信息
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
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