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Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

产品编号:4145219
规格:≥95%
包装规格:100 MG
产品类别:进口试剂
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
4145219100 MG2560
产品别名

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

Photocatalyst

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C36H22F16IrN4P
Molecular weight
1037.75
Application【应用】
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).
Other Notes【其他说明】
A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes
产品性质
Assay【测定】
≥95%
form【形式】
powder
reaction suitability
core: iridium
reagent type: catalyst
mp
>300 ℃
安全信息
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
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