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[2,2′-Bipyridine]-6-carboxylic acid hydrochloride

产品编号:4143039
CAS NO:4392-87-4
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
4143039500 MG1170
产品别名

4392-87-4

[2,2′-Bipyridine]-6-carboxylic acid hydrochloride

PPA directing group

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C11H8N2O2 · xHCl
Molecular weight
200.19 (free base basis)
MDL number
MFCD11100046
Application【应用】
Developed in the Engle lab, this 2,2′-bipyridylamide (PPA) is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PAQ (901250), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing substrate classes (e.g. 4-pentenoic acids, allylic alcohols, homoallyl amines, bis-homoallylamines) using Pd(II) catalysis.
Other Notes【其他说明】
Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization
产品性质
Quality Level【质量水平】
100
form【形式】
powder or crystals
reaction suitability
reagent type: ligand
reaction type: C-H Activation
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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