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(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
4142542 | 250 MG | 2210 |
产品别名
157904-67-1
(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene
2,2-Bis[2-(4R,5S-diphenyl-1,3-oxazolinyl)]propane
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C33H30N2O2 |
Molecular weight | 486.60 |
MDL number | MFCD24849939 |
PubChem Substance ID【PubChem化学物质编号】 | 329768502 |
NACRES | NA.22 |
Application【应用】 | (4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand:
This chiral Box ligand was most recently shown to mediate an asymmetric aminofluorination of olefins utlizing Xtalfuor-E (719439) and TREAT-HF (344648). The resulting cyclic carbamates can be readily converted into their concomitant beta-fluoro amino acids. |
Other Notes【其他说明】 | Iron(II)-Catalyzed Intramolecular Olefin Aminofluorination |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | 95% |
mp | 164-169 ℃ |
SMILES string | CC(C1=N[C@H](C2=CC=CC=C2)[C@H](C3=CC=CC=C3)O1)(C)C4=N[C@H](C5=CC=CC=C5)[C@H](C6=CC=CC=C6)O4 |
InChI | 1S/C33H30N2O2/c1-33(2,31-34-27(23-15-7-3-8-16-23)29(36-31)25-19-11-5-12-20-25)32-35-28(24-17-9-4-10-18-24)30(37-32)26-21-13-6-14-22-26/h3-22,27-30H,1-2H3/t27-,28-,29+,30+/m1/s1 |
InChI key | ZWWGNCSTEMMQOQ-XAZDILKDSA-N |
packaging【包装】 | 250 mg in amber glass bottle |
安全信息
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |