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吡啶-3-基磺基氟化物
Pyridin-3-yl sulfurofluoridate
产品别名
吡啶-3-基磺基氟化物
Pyridin-3-yl sulfurofluoridate
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C5H4FNO3S |
Molecular weight | 177.15 |
Application【应用】 | Pyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences. |
Other Notes【其他说明】 | Palladium-Catalyzed; Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | 95% |
form【形式】 | liquid |
storage temp.【储存温度】 | 2-8℃ |
packaging【包装】 | 500 mg in poly bottle |
安全信息
Pictograms【象形图】 | GHS05 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H314 |
Precautionary Statements | P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Skin Corr. 1B |
Storage Class Code【储存分类代码】 | 8B - Non-combustible, corrosive hazardous materials |
WGK | WGK 3 |