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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
4074667 | 250 MG | 1470 | |||
4074667 | 1 G | 3520 |
产品别名
27057-09-6
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
[Bis(triphenylphosphine)](o-tolyl)chloronickel
Buchwald Nickel Cross-Coupling Catalyst Precursor
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C43H37ClNiP2 |
Molecular weight | 709.85 |
PubChem Substance ID【PubChem化学物质编号】 | 329768436 |
Application【应用】 | Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers. |
Other Notes【其他说明】 | Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates |
产品性质
reaction suitability | core: nickel reagent type: catalyst |
Quality Level【质量水平】 | 100 |
mp | 195-200 ℃ |
storage temp.【储存温度】 | 2-8℃ |
SMILES string | Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7 |
InChI | 1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1 |
InChI key | QVGJKVLYWZGANE-UHFFFAOYSA-M |
packaging【包装】 | 1 g in glass bottle 250 mg in glass bottle |
安全信息
Pictograms【象形图】 | GHS07,GHS08 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H317 - H350 |
Precautionary Statements | P201 - P280 - P302 + P352 - P308 + P313 |
Hazard Classifications【危险分类】 | Carc. 1B - Skin Sens. 1 |
Storage Class Code【储存分类代码】 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
WGK | WGK 3 |