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双(4-甲氧基苯基)氯化膦

Bis(4-methoxyphenyl)chlorophosphine
产品编号:3414881
规格:85%
CAS NO:13685-30-8
包装规格:2 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
34148812 G1400
产品别名

13685-30-8

双(4-甲氧基苯基)氯化膦

Bis(4-methoxyphenyl)chlorophosphine

P,P-Bis(4-methoxyphenyl)phosphinous chloride

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C14H14ClO2P
Molecular weight
280.69
MDL number
MFCD04972301
PubChem Substance ID【PubChem化学物质编号】
329762919
NACRES
NA.22
Application【应用】
Reactant for asymmetric:
  • Allylic substitution
  • Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
  • Hydrogenation
  • Intramolecular α-arylation of aldehydes

Reactant for:
  • Alcoholysis of phosphane-boranes
  • Probing hemilabile sites of Bis(phosphine) monoxide ligands
产品性质
Quality Level【质量水平】
100
Assay【测定】
85%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
62-66 ℃
functional group【官能团】
phosphine
SMILES string
COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI
1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChI key
YTFQUBRFOJIJOZ-UHFFFAOYSA-N
packaging【包装】
2 g in glass bottle
安全信息
Pictograms【象形图】
GHS05
Signal word【警示用语:】
Danger
Hazard Statements
H314
Precautionary Statements
P280 - P305 + P351 + P338 - P310
Hazard Classifications【危险分类】
Skin Corr. 1B
Storage Class Code【储存分类代码】
8B - Non-combustible, corrosive hazardous materials
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
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