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(R)-(+)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚

(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether
产品编号:3322291
规格:96%
CAS NO:943757-71-9
包装规格:5 G,1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33222915 G818
33222911 G818
产品别名

943757-71-9

(R)-(+)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚

(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether

(R)-α,α-Diphenylprolinol trimethylsilyl ether

(2R)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine

(R)-α,α-二苯基脯氨醇三甲基硅基醚

(R)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine

(2R)-2-[二苯基[(三甲基硅基)氧基]甲基]吡咯烷

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C20H27NOSi
Molecular weight
325.52
MDL number
MFCD09265100
PubChem Substance ID【PubChem化学物质编号】
24885355
General description【一般描述】
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether is a diarylprolinol silyl ether organocatalyst.
Application【应用】
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether can be used as a catalyst to synthesize:
  • Glycofused tricyclic derivatives, which are used in the development of amyloid β-peptide diagnostic tools.
  • Cyclohexene carbaldehyde derivatives by reacting benzoylnitromethane with aliphatic enals.

产品性质
Assay【测定】
96%
optical activity【旋光性】
[α]22/D +52±5°, c = 1 in chloroform
refractive index【折射率】
n20/D 1.5509
density
1.0459 g/mL at 25 ℃
storage temp.【储存温度】
2-8℃
SMILES string
C[Si](C)(C)OC([C@H]1CCCN1)(c2ccccc2)c3ccccc3
InChI
1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1
InChI key
RSUHWMSTWSSNOW-LJQANCHMSA-N
packaging【包装】
1, 5 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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