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1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3311800 | 50 MG | 538 | |||
| 3311800 | 500 MG | 1620 |
产品别名
38465-86-0
1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
{Ir(COD)[PCH3(C6H5)2]2}PF6
[Ir(cod)(PPh2Me)2]PF6
[Ir(PMePh2)2COD]+ PF6-
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C34H38F6IrP3 |
| Molecular weight | 845.79 |
| MDL number | MFCD00064800 |
| PubChem Substance ID【PubChem化学物质编号】 | 24860482 |
| NACRES | NA.22 |
| Application【应用】 | (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates. |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | 97% |
| reaction suitability | core: iridium reagent type: catalyst |
| mp | 224 ℃ (dec.) (lit.) |
| SMILES string | [Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5 |
| InChI | 1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;; |
| InChI key | LXKHQEQLBSJJCO-JXNOXZOESA-N |
| packaging【包装】 | 50, 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H302 + H312 + H332 - H315 - H319 - H335 |
| Precautionary Statements | P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
| Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |
