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(2R,2′R-(+)-[N,N′-双(2-吡啶基甲基)]-2,2′-联吡咯烷双(乙腈)六氟锑酸铁(II)
(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3262419 | 100 MG | 992 | |||
| 3262419 | 500 MG | 3500 |
产品别名
1361315-26-5
(2R,2′R-(+)-[N,N′-双(2-吡啶基甲基)]-2,2′-联吡咯烷双(乙腈)六氟锑酸铁(II)
(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
Fe(R,R-PDP)
White-Chen catalyst
[Fe(R,R-PDP)(CH3CN)2](SbF6)2
Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C24H32F12FeN6Sb2 |
| Molecular weight | 931.90 |
| MDL number | MFCD16038114 |
| PubChem Substance ID【PubChem化学物质编号】 | 329764650 |
| NACRES | NA.22 |
| General description【一般描述】 | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. |
| Application【应用】 | Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes. Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation |
产品性质
| reaction suitability | core: iron reagent type: catalyst |
| greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
| mp | 215-226 ℃ |
| greener alternative category【环保替代产品分类】 | Aligned |
| SMILES string | [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4 |
| InChI | 1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1 |
| InChI key | XUNWHBGEOCZDBX-QSKJABRXSA-B |
| packaging【包装】 | 100, 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
