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三(1,1,1,3,3,3-六氟-2-丙基)亚磷酸

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite
产品编号:3255858
规格:98%
CAS NO:66470-81-3
包装规格:1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
32558581 G1330
产品别名

66470-81-3

三(1,1,1,3,3,3-六氟-2-丙基)亚磷酸

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite

Tris(2H-perfluoro-2-propyl) phosphite

三(2H-全氟-2-丙基)亚磷酸酯

结构式
基本信息
Linear Formula【线性分子式】
[(CF3)2CHO]3P
Molecular weight
532.06
Beilstein
2315565
MDL number
MFCD00192561
PubChem Substance ID【PubChem化学物质编号】
24865342
General description【一般描述】
Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand. It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3. It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.
Application【应用】
Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) may be used in the following processes:
  • Preparation of new phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides.
  • Preparation of nucleoside H-phosphonate units.
  • Synthesis of tetrakis(1,1,1,3,3,3-hexafluoroisopropoxy)(phenylthio)phosphorane by reacting with 1,1,1,3,3,3-hexafluoroisopropyl benzenesulfenate.
产品性质
Quality Level【质量水平】
100
Assay【测定】
98%
refractive index【折射率】
n20/D 1.300 (lit.)
bp
130 ℃ (lit.)
density
1.69 g/mL at 25 ℃ (lit.)
SMILES string
FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F
InChI
1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H
InChI key
MJOVEPJSFHDSOJ-UHFFFAOYSA-N
packaging【包装】
1 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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