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1-十四烯

1-Tetradecene
产品编号:3114964
规格:≥97.0% (GC)
CAS NO:1120-36-1
包装规格:25 ML
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
311496425 ML828
产品别名

1120-36-1

1-十四烯

1-Tetradecene

结构式
基本信息
Linear Formula【线性分子式】
CH3(CH2)11CH=CH2
Molecular weight
196.37
Beilstein
1701156
EC number【EC 号】
214-306-9
MDL number
MFCD00008981
PubChem Substance ID【PubChem化学物质编号】
57653175
NACRES
NA.22
Application【应用】
1-Tetradecene can be used as a reactant to synthesize:
  • 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
  • (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
产品性质
vapor density【蒸汽密度】
6.8 (vs air)
Quality Level【质量水平】
100
Assay【测定】
≥97.0% (GC)
autoignition temp.【自燃温度】
455 °F
refractive index【折射率】
n20/D 1.436 (lit.)
n20/D 1.436
bp
251 ℃ (lit.)
mp
−13-−11 ℃ (lit.)
density
0.775 g/mL at 25 ℃ (lit.)
SMILES string
CCCCCCCCCCCCC=C
InChI
1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChI key
HFDVRLIODXPAHB-UHFFFAOYSA-N
packaging【包装】
25 mL in glass bottle
安全信息
Pictograms【象形图】
GHS08
Signal word【警示用语:】
Danger
Hazard Statements
H304
Precautionary Statements
P301 + P310 - P331 - P405 - P501
Hazard Classifications【危险分类】
Asp. Tox. 1
Supp Hazards【补充剂危害】
EUH066
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
230.0 °F
Flash Point(C)【闪点(C)】
110 ℃
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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