氯化铈(III)七水合物

Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

Air sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.

MFCD00149634

606-073-0

CeCl₃?7H₂O

372.60 (246.48anhy)

Hygroscopic. Air Sensitive. Store under Argon. Ambient temperatures.

Crystals

Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran.

14,1997

II

36/37/38
Irritating to eyes, respiratory system and skin.

8

26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

FK5100000

是

 

H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.